Carbonyldihydridotris(triphenylphosphine)ruthenium CAS 25360-32-1

• Iden­ti­fi­ca­tion
• Prop­er­ties
• Safe­ty Data
• Spec­i­fi­ca­tions & Oth­er Information
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Iden­ti­fi­ca­tion

CAS Number

25360-32-1

Name

Carbonyldihydridotris(triphenylphosphine)ruthenium

Syn­onyms

Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)

SMILES

[C-]#[O+].c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.c1ccc(cc1)P(c2ccccc2)c3ccccc3.[RhH2]

Std­InChI

InChI=1S/3C18H15P.CO.Rh.2H/​c31-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h31-15H;;;;

Std­InChIKey

WBI­IB­WMSHZJFCB-UHF­F­­FAOYSA-N

Mol­e­c­u­lar Formula

C₅₅H₄₇OP₃Rh

Mol­e­c­u­lar Weight

919.788

Prop­er­ties

Appear­ance

Grey white to dark gray crys­talline powder

Melt­ing Point

160-162°C

Safe­ty Data

Sym­bol

GHS07

Sig­nal Word

Warn­ing

Haz­ard statements

Pre­cau­tion­ary Statements

Per­son­al Pro­tec­tive Equipment

dust mask type N95 (US), Eye­shields, Gloves

RIDADR 

NONH for all modes of transport

WGK Germany

3

Spec­i­fi­ca­tions and Oth­er Infor­ma­tion of Our Carbonyldihydridotris(triphenylphosphine)ruthenium CAS 25360-32-1

Assay

98% min

Ru

10.50% min

Stor­age

Stored at low tem­per­a­ture after vac­u­um pack­ag­ing, can not be oper­at­ed in air.

Known Appli­ca­tion

Cat­a­lyst for con­vert­ing 1,4-alkanediol to pyr­role ; Cat­a­lyst for oxi­da­tion of pri­ma­ry alco­hol to methyl ester ; Cat­a­lyst for rearrange­ment of oxime to amide ; Cat­a­lyst for C-C cou­pling by direc­tion­al C-H acti­va­tion ; Cat­a­lyst for cyclopen­tane cyclization.

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