Ru(bpy)2dppz(PF6)2 CAS 87564-74-7

• Iden­ti­fi­ca­tion
• Prop­er­ties
• Safe­ty Data
• Spec­i­fi­ca­tions & Oth­er Information
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Iden­ti­fi­ca­tion

CAS Number

87564-74-7

Name

Ru(bpy)2dppz(PF6)2

Syn­onyms

2,2′-Bipyridine, com­pd. with dipyrido[3,2-a:2′,3′-c]phenazine, ruthenium(2+) salt (2:1:1)
[Index name – gen­er­at­ed by ACD/​Name]
Bbpp-Ru
Bis(2,2′-bipyridine-N,N′)(dipyrido(3,2-a:2′,3′-c)phenazine-N4,N5)ruthenium(2+)
Bis(2,2′-bipyridyl)(dipyrido(3,2-α-2′,3′-c)phenazine)ruthenium (II)
Ru(BPY)2(DPPZ)
Ruthenium(2+), bis(2,2′-bipyridine-N,N′)(dipyrido(3,2-a:2′,3′-c)phenazine-N4,N5)-

SMILES

[Ru+2].c1ccc(-c2ccccn2)nc1.c1ccc(-c2ccccn2)nc1.c1ccc2nc3c4cccnc4c4ncccc4c3nc2c1

Std­InChI

InChI=1S/C18H10N4.2C10H8N2.Ru/c1-2-8-14-13(7-1)21-17-11-5-3-9-19-15(11)16-12(18(17)22-14)6-4-10-20-16;21-3-7-11-9(5-1)10-6-2-4-8-12-10;/h1-10H;21-8H;/q;;;+2

Std­InChIKey

YVX­­NAG­N­LAPDXJU-UHF­F­­FAOYSA-N

Mol­e­c­u­lar Formula

C38H26N8Ru

Mol­e­c­u­lar Weight

695.752

Prop­er­ties

Appear­ance

Orange red powder

Safe­ty Data

RIDADR 

NONH for all modes of transport

Spec­i­fi­ca­tions and Oth­er Infor­ma­tion of Our Ru(bpy)2dppz(PF6)2 CAS 87564-74-7

Iden­ti­fi­ca­tion Methods

1H NMR, 13C NMR, HPLC

Puri­ty

95% min

Spe­cif­ic Opti­cal Rotation

+31.0-+35.0

Loss on Drying

≤0.3%

Residue on Ignition

≤0.3%

Shelf Life

2 years

Stor­age

Store below -15°C for long-term.

Known Appli­ca­tion

1. DNA ​“Mol­e­c­u­lar Switch­es” and Probes
   Lumi­nes­cence Prop­er­ties : In aque­ous solu­tions, this ruthe­ni­um com­plex exhibits neg­li­gi­ble lumi­nes­cence (due to quench­ing by water mol­e­cules). How­ev­er, when it binds to the DNA dou­ble helix struc­ture — specif­i­cal­ly with­in the major or minor grooves — or inter­ca­lates between base pairs, it emits intense flu­o­res­cence.
   Diag­nos­tic Appli­ca­tions : Used to detect the pres­ence and con­cen­tra­tion of DNA, as well as changes in DNA con­for­ma­tion. Because it remains ​“dark” in its unbound state and becomes ​“bright” upon bind­ing, obser­va­tion can be per­formed with­out the need to wash away unbound probes.
2. Bioimag­ing and Cel­lu­lar Sens­ing
   Cell Stain­ing : Cap­i­tal­iz­ing on its high pho­to­phys­i­cal sta­bil­i­ty and large Stokes shift, it is employed for imag­ing live cells.
   Spe­cif­ic Organelle Tar­get­ing : Upon mod­i­fi­ca­tion, these ruthe­ni­um com­plex­es are often engi­neered as biosen­sors specif­i­cal­ly tar­get­ed to mito­chon­dria or cell nuclei, enabling the mon­i­tor­ing of microen­vi­ron­men­tal changes with­in the cell.
3. Pho­to­dy­nam­ic Ther­a­py (PDT) Research
   Pho­to­sen­si­tiz­ers : Under illu­mi­na­tion, ruthe­ni­um com­plex­es are capa­ble of gen­er­at­ing reac­tive oxy­gen species (ROS), such as sin­glet oxy­gen ($^1O_2$).
   Anti­tu­mor Research : Researchers lever­age the com­plex­es’ strong affin­i­ty for DNA and their pho­to­sen­si­tiz­ing prop­er­ties to explore their poten­tial as pho­to­sen­si­tiz­ing drugs for the pre­ci­sion tar­get­ing of can­cer cells, induc­ing DNA dam­age in tumor cells through irra­di­a­tion with spe­cif­ic wave­lengths of light.
4. Elec­tron and Ener­gy Trans­fer
   Pho­to­catal­y­sis Research : Ruthe­ni­um com­plex­es pos­sess excel­lent redox poten­tials and are fre­quent­ly uti­lized to inves­ti­gate pho­­to-induced elec­tron trans­fer (PET) process­es.
   Arti­fi­cial Pho­to­syn­the­sis : In chem­i­cal lab­o­ra­to­ries, they serve as com­mon­ly used mod­el mol­e­cules for mim­ic­k­ing nat­ur­al pho­to­syn­thet­ic reac­tion cen­ters and study­ing ener­gy trans­fer mechanisms.
5. Nan­otech­nol­o­gy and Biosen­sors
   Mod­i­fied Elec­trodes : Used in the fab­ri­ca­tion of elec­tro­chemi­lu­mi­nes­cence (ECL) sen­sors for the detec­tion of trace amounts of bio­mol­e­cules or met­al ions.
   DNA Nanoma­chines : Employed in the con­struc­tion of DNA nan­ode­vices, where they func­tion as indi­ca­tors of struc­tur­al sta­bil­i­ty or as sig­nal out­put units.

Gen­er­al View of Documents

Links

This prod­uct is devel­oped by our R&D com­pa­ny Wat­son Bio Ltd (https://​www​.wat​son​-bio​.com/).

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