(S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl CAS 133545-17-2

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• Prop­er­ties
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Iden­ti­fi­ca­tion

CAS Number

133545-17-2

Name

(S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl//(S)-(-)-MeO-BIPHEP

Syn­onyms

(6,6′-Dimethoxy-2,2′-biphenyldiyl)bis(diphenylphosphin) [Ger­man] [ACD/IUPAC Name]
(6,6′-Dimethoxy-2,2′-biphenyldiyl)bis(diphenylphosphine) [ACD/IUPAC Name]
(6,6′-Diméthoxy-2,2′-biphényldiyl)bis(diphénylphosphine) [French] [ACD/IUPAC Name]
(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
(R)-(+)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
(R)-(+)-MeO-BIPHEP
(S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
(S)-(-)-MeO-BIPHEP
133545-16-1 [RN]
133545-17-2 [RN]
4790083
MFCD03095430
Phos­phine, 1,1′-(6,6′-dimethoxy[1,1′-biphenyl]-2,2′-diyl)bis[1,1-diphenyl- [ACD/​Index Name]
SL-A101-1
SL-A101-2
(R)-(+)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
(R)-(6,6′-Dimethoxy-[1,1′-biphenyl]-2,2′-diyl)bis(diphenylphosphine)
(R)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl
(RS)-(6,6′-dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
(S)-(-)-(6,6′-Dimethoxybiphenyl-2,2′-diyl)bis(diphenylphosphine)
(S)-(6,6′-dimethoxy-[1,1′-biphenyl]-2,2′-diyl)bis(diphenylphosphine)
[133545-16-1]
[2-(2-diphenylphosphanyl-6-methoxyphenyl)-3-methoxyphenyl]-diphenylphosphane
[2′-(DIPHENYLPHOS­PHANYL)-6,6′-DIMETHOXY-[1,1′-BIPHENYL]-2-YL]DIPHENYLPHOS­PHANE
{2-[2-(DIPHENYLPHOS­PHANYL)-6-METHOXYPHENYL]-3-METHOXYPHENYL}DIPHENYLPHOS­PHANE
133577-92-1 [RN]
97% (R)-MeO-BIPHEP
97% (S)-MeO-BIPHEP
eth­yl 3-[benzyl-(2-ethoxy-2-oxoethyl)amino]propanoate
http:////www.amadischem.com/proen/555396/
http:////www.amadischem.com/proen/610521/
meo-biphep
Phos­phine, (6,6′-dimethoxy[1,1′-biphenyl]-2,2′-diyl)bis[diphenyl-
R(+)-2 2′-BIS-(DIPHENYLPHOS­PHI­NO)-6 6′-
S(-)-2 2-BIS-(DIPHENYLPHOS­PHI­NO)-6 6-DIM
Tri(furan-2-yl)phosphine
tris(2-furyl)phosphane;Tri(2-furyl)phosphine

SMILES

COc1cccc(c1c2c(cccc2P(c3ccccc3)c4ccccc4)OC)P(c5ccccc5)c6ccccc6

Std­InChI

InChI=1S/C38H32O2P2/c1-39-33-25-15-27-35(41(29-17-7-3-8-18-29)30-19-9-4-10-20-30)37(33)38-34(40-2)26-16-28-36(38)42(31-21-11-5-12-22-31)32-23-13-6-14-24-32/h3-28H,1-2H3

Std­InChIKey

KRJVQCZJJ­­SUH­HO-UHF­F­­FAOYSA-N

Mol­e­c­u­lar Formula

C₃₈H₃₂O₂P₂ 

Mol­e­c­u­lar Weight

582.61

Beil­stein Reg­istry Number

4790083 

MDL Number

MFCD03095430

Prop­er­ties

Appear­ance

Off-white sol­id

Safe­ty Data

Per­son­al Pro­tec­tive Equipment

Eye­shields, Gloves, type N95 (US)

RIDADR 

NONH for all modes of transport

WGK Germany

3

Spec­i­fi­ca­tions and Oth­er Infor­ma­tion of Our (S)-(-)-2,2′-Bis(diphenylphosphino)-6,6′-dimethoxy-1,1′-biphenyl CAS 133545-17-2

Iden­ti­fi­ca­tion Methods

HPLC

Assay

98% min

Assay(ee)

99%min

Sol­u­bil­i­ty

≤1%(DCM)

Shelf Life

2 years

Stor­age

Under room tem­per­a­ture away from light

Known Appli­ca­tion

Used as a catalyst.

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