(R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylph osphine CAS 155830-69-6

• Iden­ti­fi­ca­tion
• Prop­er­ties
• Safe­ty Data
• Spec­i­fi­ca­tions & Oth­er Information
• Links
• Quick Inquiry

Iden­ti­fi­ca­tion

CAS Number

155830-69-6

Name

(R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylph osphine

Syn­onyms

(2R)-1-[(1R)-1-[Bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)ferrocene (acc to CAS)
1,2,3,4,5-Cyclopentanepentayl, com­pd. with 1-[(1R)-1-[bis(1,1-dimethylethyl)phosphino]ethyl]-2-(diphenylphosphino)-1,2,3,4,5-cyclopentanepentayl, iron salt (1:1:1) [ACD/​Index Name]
155830-69-6 [RN]
Josiphos SL-J002-1
MFCD01074442
(R)-1-[(S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylphosphine

SMILES

C[C@H]([C]1[CH][CH][CH][C]1P(c2ccccc2)c3ccccc3)P(C(C)(C)C)C(C)(C)C.[CH]1[CH][CH][CH][CH]1.[Fe]

Std­InChI

InChI=1S/C27H40P2.C5H10.Fe/c1-21(29(26(2,3)4)27(5,6)7)24-19-14-20-25(24)28(22-15-10-8-11-16-22)23-17-12-9-13-18-23;1-2-4-5-3-1;/h8-13,15-18,21,24-25H,14,19-20H2,1-7H3;1-5H2;/t21-,24?,25?;;/m1../s1

Std­InChIKey

KEER­M­MZARKKV­­BY-XOBZD­M­SASA-N

Mol­e­c­u­lar Formula

C₃₂H₄₀FeP₂

Mol­e­c­u­lar Weight

542.45

MDL Number

MFCD01074442

Prop­er­ties

Appear­ance

Orange­crys­talline powder

Safe­ty Data

WGK Germany

3

Spec­i­fi­ca­tions and Oth­er Infor­ma­tion of Our (R)-1-[(1S)-2-(Diphenylphosphino)ferrocenyl]ethyldi-tert-butylph osphine CAS 155830-69-6

Iden­ti­fi­ca­tion Methods

1H-NMR ; 31P-NMR

Puri­ty

98% min

EE content

≥99.0%

Spe­cif­ic rotation

-412°±15°(c＝0.5,CHCl3)

Shelf Life

2 years

Stor­age

The prod­uct is easy to be slow­ly oxi­dized when exposed to the air, and it needs to be vac­u­um-packed and refrig­er­at­ed for long-term storage.

Known Appli­ca­tion

Often used with pre­cious met­al pal­la­di­um com­pounds for C-C cou­pling and C-N cou­pling ; with pre­cious met­al rhodi­um and ruthe­ni­um com­pounds for asym­met­ric syn­the­sis, etc.

Links

This prod­uct is devel­oped by our R&D com­pa­ny Warshel Chem­i­cal Ltd (https://​www​.warshel​.com/).

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